Ingredients: A handful of ice cubes 30ml good quality vodka 30ml Tia Maria or Kahlua One espresso shot or 35ml of fresh espresso coffee. – If you want to add sugar syrup, prepare this whilst the glasses are chilling. Combine the sugar and water, stirring to dissolve. EM-350. Look no further. Add the espresso and stir to ensure the sugar dissolves. The perfect espresso martini ingredients. 2. Close â¢ Posted by 36 minutes ago. I can easily get Kahlua or Tia Maria. First make your espresso and let it cool. Pour equally into 3 martini glasses. Add the Vodka, stirring well to combine. Try and find a bar that's well stocked and has several of them and do a side by side taste test. Classic Espresso Martini. Whisk together the butter and sugar with an electric mixer until pale and fluffy. – Add ice, Kahlua, vodka, and fresh espresso into a cocktail shaker.